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The Mayan blues: Unravelling a mystery

Date: Apr 15, 2013

Author: David Bradley

A team of chemists in Spain has used kinetic analysis of cyclic voltammetry, infrared and ultraviolet spectroscopic data to re-affirm their 2006 hypothesis regarding how ancient artists got the Maya blues.

Read More thumbnail image: The Mayan blues Unravelling a mystery

Panacea: Liquid grace or toxic snake oil?

Date: Apr 15, 2013

Author: David Bradley

Proton NMR spectroscopy and energy dispersive X-ray fluorescence (EDXRF) spectroscopy have been used to analyse snake oil, elixirs, panaceas and other quackery found in medicines prescribed from the 18th century onwards. It turns out that many of these often-patented nostrums contained highly dangerous levels of toxic elements including arsenic, mercury and lead, as well as cocaine, heroin and high levels of alcohol.

Read More thumbnail image: Panacea Liquid grace or toxic snake oil

Vendor Column: Advantages of a Scalable Chromatography Data System

Date: Apr 10, 2013

Author: Chris Stumpf

In this second article in the latest series, Waters Corporation's Chris Stumpf continues the discussion regarding chromatography data systems with respect to its rationlization and scalability within a corporation.

Read More thumbnail image: Vendor Column Advantages of a Scalable Chromatography Data System

Journal Highlight: Visible and near infrared fluorescence spectral flow cytometry

Date: Apr 8, 2013

Author: spectroscopyNOW

Spectral flow cytometry instruments, software and experimental design that allow spectral flow cytometry to be integrated with conventional flow cytometry approaches are described and several near infrared emitting fluorophores are evaluated.

Read More thumbnail image: Journal Highlight Visible and near infrared fluorescence spectral flow cytometry

Journal Highlight: Soft ionization mass spectroscopy: Insights into the polymerization mechanism

Date: Apr 8, 2013

Author: spectroscopyNOW

This review is focused on the use of soft ionization mass spectroscopy to characterize the products of polymerization/degradation reactions thereby yielding mechanistic information.

Read More thumbnail image: Journal Highlight Soft ionization mass spectroscopy Insights into the polymerization mechanism

Journal Highlight: A tunable multicolour rainbow filter for improved stress and dislocation density field mapping in polycrystals using X-ray Laue microdiffraction

Date: Apr 8, 2013

Author: spectroscopyNOW

A new rainbow method for measuring the energy profiles of Laue spots while remaining in the white-beam mode proceeds in the opposite way compared to a monochromator-based method, by simultaneously removing several sharp energy bands from the incident beam.

Read More thumbnail image: Journal Highlight A tunable multicolour rainbow filter for improved stress and dislocation density field mapping in polycrystals using X-ray Laue microdiffraction

Journal Highlight: NMR quadrupole liouvillians for arbitrary spin: Exact symbolic expressions and perturbation solutions

Date: Apr 1, 2013

Author: spectroscopyNOW

The NMR of quadrupolar nuclei with half-integer spins, which is described by treating the quadrupole interaction with second-order perturbation theory, has been elaborated on by calculating the transitions directly without the requirement of knowing the operators and wavefunctions.

Read More thumbnail image: Journal Highlight NMR quadrupole liouvillians for arbitrary spin Exact symbolic expressions and perturbation solutions

Chocolate threats: Carcinogenic PAHs

Date: Apr 1, 2013

Author: Steve Down

Several polycyclic aromatic hydrocarbons have been determined in chocolate by GC/MS following a specially devised SPME procedure, giving a more sensitive method than an HPLC procedure developed in 2012 by the same research group.

Read More thumbnail image: Chocolate threats Carcinogenic PAHs

Journal Highlight: Trace level detection and identification of nitro-based explosives by surface-enhanced Raman spectroscopy

Date: Apr 1, 2013

Author: spectroscopyNOW

Surface-enhanced Raman spectroscopy has been used to detect and identify traces of pentaerythritol tetranitrate (PETN), ethylene glycol dinitrate (EGDN), cyclotrimethylene-trinitramine (RDX) and trinitrotoluene (TNT) using commercially available substrates.

Read More thumbnail image: Journal Highlight Trace level detection and identification of nitro-based explosives by surface-enhanced Raman spectroscopy

Journal Highlight: Analysis of audio magnetic tapes with sticky shed syndrome by ATR-FTIR

Date: Apr 1, 2013

Author: spectroscopyNOW

ATR-FTIR spectroscopy was used to identify spectroscopic markers for sticky shed syndrome in audio magnetic tapes with a poly(ester urethane) binder layer that are held in Library of Congress collections.

Read More thumbnail image: Journal Highlight Analysis of audio magnetic tapes with sticky shed syndrome by ATR-FTIR
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